Keeping Water In: The Simple Trick Boosting Sodium‑Ion Battery Performance

Scientists at the University of Surrey reported that retaining water within sodium vanadium oxide – forming nanostructured sodium vanadate hydrate (NVOH) – delivers higher capacity and fast charging, and even operates in salt water for electrochemical desalination. Full details appear in the Journal of Materials Chemistry A and the University of Surrey press release.

Sodium‑ion • NVOH • Desalination
University of Surrey graphic depicting NVOH battery tests in aqueous NaCl
Feature image: University of Surrey — NVOH tested in organic cells and salt water.

Specific capacity (low current)

≈ 280 mAh·g⁻¹ @ 10 mA·g⁻¹

Lab half‑cell

High‑rate capacity

≈ 70.9 mAh·g⁻¹ @ 1000 mA·g⁻¹

Lab half‑cell

Cycling mentioned

> 400 cycles (reported)

Press release

Full cell capacity

≈ 70 mAh·g⁻¹

C@V₂O₃ counter

Interlayer spacing

Wider → more Na⁺ sites

Low‑rate capacity

≈ 280 mAh·g⁻¹

High‑rate response

≈ 70.9 mAh·g⁻¹ @ 1000 mA·g⁻¹

Aqueous test

Na⁺ extraction; works in NaCl(aq)

Quote: “Our results were completely unexpected…” — Dr. Daniel Commandeur.

Interlayer spacing

Narrower → fewer Na⁺ sites

Observed capacity

Lower vs NVOH under same test

Rate capability

Lower vs NVOH

Aqueous test

Not the focus of this study

Drying (heat treatment) contracts the lattice by removing crystal water.

Try it: Charge rate vs. salt removal (illustrative)

Rate: 10 mA·g⁻¹
Na⁺ removed (relative)
In tests, NVOH extracted Na⁺ while a graphite electrode captured Cl⁻ (electrochemical desalination).
≈ 280 mAh·g⁻¹ @ 10
≈ 70.9 mAh·g⁻¹ @ 1000
Aqueous cell capable of NaCl removal
This is a simple visual; it is not a quantitative simulator.

Keeping Water In: Scientists at the University of Surrey discovered that leaving water inside sodium‑ion batteries improves performance — a finding that could accelerate development of cheaper, more sustainable energy storage. The team worked with sodium vanadium oxide and, by retaining its crystal water to form nanostructured sodium vanadate hydrate (NVOH), observed much higher charge storage and faster rates.

The “wet” material achieved a specific capacity of approximately 280 mAh·g⁻¹ at low current and maintained about 70.9 mAh·g⁻¹ at high current. Stability over more than 400 charge cycles was reported. Tests in salt water found that NVOH removed sodium while a graphite electrode removed chloride, indicating electrochemical desalination. Details are available from the University of Surrey release and the peer‑reviewed paper in J. Mater. Chem. A.

“Our results were completely unexpected… People usually heat‑treat it to remove the water… We decided to challenge that assumption.” — Dr. Daniel Commandeur, Surrey Future Fellow.

Context for commercialisation: CATL announced its Naxtra sodium‑ion battery at ≈175 Wh·kg⁻¹, with mass production scheduled to begin in December 2025. This places sodium‑ion development on a clearer path while research like NVOH focuses on electrode behaviour and manufacturability.

Quick check

Which value is the reported low‑rate specific capacity for NVOH?
200 mAh·g⁻¹
≈ 280 mAh·g⁻¹ @ 10 mA·g⁻¹
70.9 mAh·g⁻¹ @ 1000 mA·g⁻¹
500 mAh·g⁻¹

The study and press release described NVOH performance metrics, salt‑water operation, and a laboratory desalination setup. The commercial context from CATL was stated with an energy density figure and a production schedule. These points were presented above for clarity.

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